H2SO4 H2O///Hg(OAC).. - form OH on most substituted atom , BH3 NaOH H2O2 (alkene) - form OH on least substituted atom, OsO4 - form two OH , Br2 H2O - form OH and halogen (w steriochem), O3 /s\ (alkene) - form ketone, H2SO4 H2O (alkyne) - form carbonyl, BH3 NaOH H2O2 (alkyne) - form anti marko ketone, ozonolysis - break C-C, reaction with acetylide ion & NH2 - form C-C, O3 H2O2 - O3 H2O - form carboxylic acid, HBr - add X on alkene, Br2 - add two X on alkene, H2pd - alkene-> alkane or alkyne ->alkane, Br2 1eq - add 2 X on alkyne, Br2 2eq - add 4 X on alkyne, H2 Lindlars - alkyne -> cis alkene, Na NH2 - alkyne -> trans alkene, Br2 hv or triangle - add X without changing if its single-double-triple bond, NBS ROOR hv - add X on carbon next to alkene, HBr ROOR hv - add X on least substituted carbon of alkene, O3 h2o2 oxidative - break a ring,

CINDY OCHEM PT2

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